Appearance: colorless clear liquid Odor: Odor stimulation Odor Threahold :0.35~0.92mg/m3 Ph valve: / Melting point/freezing point: 19.5-21.5℃ Initial boiling point and boiling range: 247℃ Flash point: 121 ℃ Upper/lower flammability or explosive limits: Upper explosion limit: 9.5%(V) Lower explosion limit: 0.9%(V) Relative density: 1.22(water=1) Water solubility: insoluble

TOLUENE DIISOCYANATE 80/20 1. Identification Product Name: TOLUENE DIISOCYANATE Recommended use of the chemical and restrictions on used: For the manufacture of soft polyurethane foam, paint,rubber and adhesive materials. 2. Hazards Identification Classification of the substance or mixture： Toxicity ( inhalation ) Category 2, Skin corrosion/irritation Category 2, Eye Irritation Category 2A, Sensitization-respiratory Category 1, Sensitization-skin Category 1, Carcinogenicity Category 2, Specific target organ ( respiratory organs ) toxicity-single exposure Category 3, Hazardous to the aquatic environment-long-term hazard Category 3. GHS Label elements,including precautionary statements： Signal word: Danger Hazard statement(s): Fatal if inhaled. May cause skin's irritation. May cause eye's severe irritation. May cause allergy or asthma symptoms or breathing difficulties if inhales. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Precautionary statement(s): Prevention: Obtain specific instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Do not eat 、drink or smoke when using this product. Avoiding breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing/eye protection/face protection. Such as inadequate ventilation, wear respiratory protection. Wash thoroughly after handling. The contaminated work clothes may not be brought out, avoid release to the environment. Emergency: Such as skin contamination: wash with plenty of soap and water. In case of skin irritation or rash: call a poison/doctor. Remove contaminated clothing, clean the rear can be re used. If inhaled: the victim will be transferred to the fresh air, to maintain a comfortable position in the breath. If there is a respiratory disease, call the interpretation center or doctor. Such as into the eyes: rinse with water carefully for a few minutes. If wearing contact lenses and can be easily removed, remove contact lenses. Continue washing. If still feel eye irritation: call a poison/doctor. Such as exposure to or have doubts: call a poison/doctor. Collection overflow. Storage: Store in well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container to in accordance with national regulations. 3. Composition/Information on Ingredients Chemical Name: TOLUENE DIISOCYANATE CAS: 26471-62-5 toluene-2,4-diisocyanate 80% toluene-2,6-diisocyanate 20% 4. First Aid Measures Skin contact: Remove contaminated clothing and rinse with soap and plenty of water. Medical treatment Eye Contact: Rinse eyes with cold water thoroughly for 15 minutes, and send to hospital immediately for treatment. Ingestion: Drink water to dilute, and give medical treatment. Inhalation: quickly from the scene to fresh air. Maintain airway patency. If breathing is difficult, give oxygen. If breathing stops, immediately perform artificial respiration. Medical treatment. 5. Fire Fighting Measures Hazardous Characteristics: flammable, and its vapor can form explosive mixtures with air, In case of fire, high-heat combustion and explosion occurred. Hazardous Decomposition Products: carbon monoxide, nitrogen oxides and trace amounts of hydroxide. Extinguishing methods: choking, isolating, cooling containers. Extinguishing agent: foam, dry powder, carbon dioxide, sand. 6. Accidental Release Measures Rapid evacuation from air leaks to safety areas, isolation and tight access to staff cleanliness, personnel restrictions should wear protective clothing, gloves, boots and respirator isolation. If possible, cut off leakage sources to minimize exposure. Eliminate regional air leakage from all fire sources and leakage areas, do not contact leaks to diffuse or leak into drains. Spray foam having a protein surface to reduce vapor concentration in the presence of a large-area leak, covered with sand or commercially non reactive material. 7. Handling and Storage Handling Precautions: the operators wear gas mask, protective glasses, protective clothing, rubber gloves. Points for attention on storage: should be stored in a cool, dry, well ventilated warehouse. 8. Exposure Controls/Personal Protection Control parameters: China MAC (mg/m3):0.2 America: CGIH TLV-TWA(mg/m3)：0.036,STEL(mg/m3):0.14 OEL-FRANCE:VME 0.01 ppm (0.08mg/m3), VLE 0.02 ppm (0.16mg/m3),JAN1999;OEL-SWEDEN:TWA 0.005 ppm, CEILING 0.01 ppm, JAN1999; OEL-UNITED KINGDOM:TWA 0.02mg(NCO)/M3,STEL 0.07mg(NCO)/M3,SEP2000 Project control: strictly closed, provide full local exhaust. Provide safe shower and eye washing equipment. Respiratory protection: excessive concentration of air, must wear self suction filter mask (half mask). When emergency rescue or evacuation, should wear air respirator. Eye protection: wear chemical safety goggles Body protection: wear penetrating clothing Hand protection: wear rubber gloves Other protection: smoking, eating and drinking at work. Work finished, thoroughly cleaned. Separate clothes contaminated by poison, after washing spare. Maintain good hygiene habits. 9.Physical/Chemical Properties Appearance: colorless clear liquid Odor: Odor stimulation Odor Threahold :0.35~0.92mg/m3 Ph valve: / Melting point/freezing point: 19.5-21.5℃ Initial boiling point and boiling range: 247℃ Flash point: 121 ℃ Upper/lower flammability or explosive limits: Upper explosion limit: 9.5%(V) Lower explosion limit: 0.9%(V) Relative density: 1.22(water=1) Water solubility: insoluble 10. Stability and Reactivity Reactive: / Chemical stability: can react with strong oxidant. Encounter heat, open fire, sparks will fire. Risk response possibility:/ Conditions to be avoided: heat, flame and spark. Extreme temperature and direct daylight. Incompatible substances. Incompatible substances and materials: strong oxidizing agents. Hazardous decomposition products: carbon oxides, cyanide, nitrogen oxides. 11. Toxicological Information Oral Toxicity: LD50 (rat) = 5840mg/kg Dermal toxicity: LD50 (rats)> 9.4 mg / kg delayed allergic reactions, skin stimulation. Eye effect: strong irritant (rabbit) Inhalation toxicity: LC50 (rat) = 462 mg/cm3/1 hours ?? LC50 (rat) = 100 mg/cm3/4 hours ?? Chronic inhalation of 0.7 mg/cm3 (0.1ppm) or more weight loss caused by animals, respiratory diseases, allergic and immune changes. Carcinogenicity: 0.35 and 1.07 mg/cm3 Group 113 weeks non-carcinogenic, but oral carcinogenic 12. Ecological Information Ecotoxicity: environmental hazards, easy to aggregate. Should pay attention to the health hazards of air and water pollution. 13. Waste Disposal Nature of waste: hazardous waste. Waste Disposal Method: Treatment with controlled burning. 14. Transport Information UN Number: 2078 UN proper shipping name：TOLUENE DIISOCYANATE Transport hazard class (es): 6.1 Packing Group: II Environmental hazards: No 15. Regulatory Information TOLUENE DIISOCYANATE (CAS: 26471-62-5) is found on the following regulatory lists: China ( Hong Kong) Fire Service Department-List of Dangerous Goods”,” China ( Hong Kong) Occupational Exposure Limits”,” China Catalog of Hazardous Chemicals”,” China Classification and Labeling of Dangerous Chemical Substances”,” China Dangerous Chemicals Names List”,” China First Imported Class Two Chemical List”,” China Highly Toxic Product Chemicals”,” China Inventory of Existing Chemical Substances”,” China List of Extremely Toxic Chemicals”,” China Occupational Exposure Limits for Hazardous Agents in the Workplace”,” GESAMP/EHS Composite List- GESAMP Hazard Profiles”,” IMO IBC Code Chapter 17: Summary of minimum requirements”,” International Agency for Research on Cancer(IARC)- Agents Reviewed by the IARC Monographs”,” International Council of Chemical Associations(ICCA)- High Production Volume List”,” OECD List of High Production Volume(HPV) Chemicals” This safety data sheet is in compliance with the following national standards: GB16483- 2008,GB13690-2009,GB6944-2005,GB/T15098-2008,GB18218-2009,GB15258- 2009,GB6944-2005,GB190-2009,GB191-2009,GB12268-2008,GA57- 1993,GB/T15098-2008,GBZ 2-2007 as well as the following national regulations: Dangerous Goods Transport Administrative Regulation, Dangerous Chemicals Safety Administrative Regulation, United Nations Regulations on the Transport of Dangerous Goods(UN RTDG).